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Functional groups can have decisive influence on the chemical and physical properties of organic compounds. Physical organic chemistry - Wikipedia. Physical organic chemistry, a term coined by Louis Hammett in 1. Specific focal points of study include the rates of organic reactions, the relative chemical stabilities of the starting materials, reactive intermediates, transition states, and products of chemical reactions, and non- covalent aspects of solvation and molecular interactions that influence chemical reactivity. Such studies provide theoretical and practical frameworks to understand how changes in structure in solution or solid- state contexts impact reaction mechanism and rate for each organic reaction of interest. Physical organic chemists use theoretical and experimental approaches work to understand these foundational problems in organic chemistry, including classical and statistical thermodynamic calculations, quantum mechanical theory and computational chemistry, as well as experimental spectroscopy (e. NMR), spectrometry (e. MS), and crystallography approaches. The field therefore has applications to a wide variety of more specialized fields, including electro- and photochemistry, polymer and supramolecular chemistry, and bioorganic chemistry, enzymology, and chemical biology, as well as to commercial enterprises involving process chemistry, chemical engineering, materials science and nanotechnology, and drug discovery. Physical organic chemistry is the study of the relationship between structure and reactivity of organic molecules. More specifically, physical organic chemistry applies the experimental tools of physical chemistry to the study of the structure of organic molecules and provides a theoretical framework that interprets how structure influences both mechanisms and rates of organic reactions. It can be thought of as a subfield that bridges organic chemistry with physical chemistry. Physical organic chemists use both experimental and theoretical disciplines such as spectroscopy, spectrometry, crystallography, computational chemistry, and quantum theory to study both the rates of organic reactions and the relative chemical stability of the starting materials, transition states, and products. This includes experiments to measure or determine the enthalpy (. Chemists may use various chemical and mathematical analyses, such as a Van 't Hoff plot, to calculate these values. Empirical constants such as bond dissociation energy, standard heat of formation (. For complex molecules, a . This type of analysis is often referred to as Benson group increment theory, after chemist Sidney Benson who spent a career developing the concept. Group increment data are available for radical systems. Physical organic chemists use conformational analysis to evaluate the various types of strain present in a molecule to predict reaction products. The A- value is the difference in the Gibbs' free energy between the axial and equatorial forms of substituted cyclohexane, and by adding together the A- values of various substituents it is possible to quantitatively predict the preferred conformation of a cyclohexane derivative. In addition to molecular stability, conformational analysis is used to predict reaction products. One commonly cited example of the use of conformational analysis is a bi- molecular elimination reaction (E2). This reaction proceeds most readily when the nucleophile attacks the species that is antiperiplanar to the leaving group. A molecular orbital analysis of this phenomenon suggest that this conformation provides the best overlap between the electrons in the R- H . Such interactions include, but are not limited to, hydrogen bonding, electrostatic interactions between charged molecules, dipole- dipole interactions, polar- . In addition, the hydrophobic effect. The precise physical origin of the hydrophobic effect originates from many complex interactions, but it is believed to be the most important component of biomolecular recognition in water. The study of non- covalent interactions is also used to study binding and cooperativity in supramolecular assemblies and macrocyclic compounds such as crown ethers and cryptands, which can act as hosts to guest molecules. Acid. Organic chemists are primarily concerned with Br. Chemists use a series of factors developed from physical chemistry - - electronegativity/Induction, bond strengths, resonance, hybridization, aromaticity, and solvation. In general, interactions between molecules of the same type are preferred. That is, hard acids will associate with hard bases, and soft acids with soft bases. The concept of hard acids and bases is often exploited in the synthesis of inorganic coordination complexes. Kinetics. Unlike thermodynamics, which is concerned with the relative stabilities of the products and reactants (. Chemists have also used the principle of thermodynamic versus kinetic control to influence reaction products. Rate laws. The rate law provides a quantitative relationship between the rate of a chemical reaction and the concentrations or pressures of the chemical species present. The experimentally determined rate law refers to the stoichiometry of the transition state structure relative to the ground state structure. Determination of the rate law was historically accomplished by monitoring the concentration of a reactant during a reaction through gravimetric analysis, but today it is almost exclusively done through fast and unambiguous spectroscopic techniques. In most cases, the determination of rate equations is simplified by adding a large excess (. A catalyst participates in the chemical reaction but is not consumed in the process. Catalysts may also influence a reaction rate by changing the mechanism of the reaction. Isotopic substitution changes the potential energy of reaction intermediates and transition states because heavier isotopes form stronger bonds with other atoms. Atomic mass affects the zero- point vibrational state of the associated molecules, shorter and stronger bonds in molecules with heavier isotopes and longer, weaker bonds in molecules with light isotopes. Substituents can exert an effect through both steric and electronic interactions, the latter of which include resonance and inductive effects. The polarizability of molecule can also be affected. Most substituent effects are analyzed through linear free energy relationships (LFERs). The most common of these is the Hammett Plot Analysis. The parameters of the Hammett plots are sigma (. Therefore, two new scales were produced that evaluate the stabilization of localized charge through resonance. Hammett analysis can be used to help elucidate the possible mechanisms of a reaction. For example, if it is predicted that the transition state structure has a build- up of negative charge relative to the ground state structure, then electron- donating groups would be expected to increase the rate of the reaction. Steric and polar effects are analyzed through Taft Parameters. Changing the solvent instead of the reactant can provide insight into changes in charge during the reaction. The Grunwald- Winstein Plot provides quantitative insight into these effects. A change in solvent can also allow a chemist to influence the thermodynamic or kinetic control of the reaction. Reactions proceed at different rates in different solvents due to the change in charge distribution during a chemical transformation. Solvent effects may operate on the ground state and/or transition state structures. In non- polar aprotic solvents, the enol form is strongly favored due to the formation of an intramolecular hydrogen- bond, while in polaraprotic solvents, such as methylene chloride, the enol form is less favored due to the interaction between the polar solvent and the polar diketone. However, the faster rate of cis- trans isomerization in THF results in a loss of stereochemical purity. This is a case where understanding the effect of solvent on the stability of the molecular configuration of a reagent is important with regard to the selectivity observed in an asymmetric synthesis. Quantum chemistry. Due to these limitations, a true understanding of physical organic chemistry requires a more rigorous approach grounded in particle physics. Quantum chemistry provides a rigorous theoretical framework capable of predicting the properties of molecules through calculation of a molecule. Particles are defined by their associated wavefunction, an equation which contains all information associated with that particle. This information is extracted from the wavefunction through the use of mathematical operators. Time- independent Schr. In the various forms of the Schr. For this reason, nuclei are of negligible size in relation to much lighter electrons and are treated as point charges in practical applications of quantum chemistry. Due to complex interactions which arise from electron- electron repulsion, algebraic solutions of the Schr. In systems with multiple electrons, an overall multielectron wavefunction describes all of their properties at once. Such wavefunctions are generated through the linear addition of single electron wavefunctions to generate an initial guess, which is repeatedly modified until its associated energy is minimized. Thousands of guesses are often required until a satisfactory solution is found, so such calculations are performed by powerful computers. Importantly, the solutions for atoms with multiple electrons give properties such as diameter and electronegativity which closely mirror experimental data and the patterns found in the periodic table. The solutions for molecules, such as methane, provide exact representations of their electronic structure which are unobtainable by experimental methods. Similarly, the true electronic structure of 1,3- butadiene shows delocalized . An example of how electronic structure determination is a useful tool for the physical organic chemist is the metal- catalyzed dearomatization of benzene. Facebook. Entfernen. Wir verwenden Cookies, um Inhalte zu personalisieren, Werbeanzeigen ma. Wenn du auf unsere Webseite klickst oder hier navigierst, stimmst du der Erfassung von Informationen durch Cookies auf und au. Weitere Informationen zu unseren Cookies und dazu, wie du die Kontrolle dar. The Weight Trainer's Bodybuilding Diet. So much advice about bodybuilding diets is off the mark. Weight training and bodybuilding nutrition are sciences like anything else in the fitness sciences: it. This, however, is where the detail becomes very important. Start with a Healthy Diet. Although various diets like Atkins and South Beach and Ornish have become popular, the general consensus among dietitians and nutritionists is that a healthy diet is somewhat different - - less stringent in requirements and more balanced across the major nutrients. You can see the key recommendations for the general population in Dietary Guidelines for Americans. With the right plan and the right discipline, you can get seriously shredded in just 28 days. This diet will help you achieve that goal. Use our search options to find the perfect plan that lines up with your goals AND your schedule. We've got over 400 workout plans a. Free Diet Training Programs download from Powerzone Nutrition Sport Supplements online Guidelines from other western countries like the UK and Australia are similar. In summary, the recommendations are: Eat plenty of fruit and vegetables, whole grains, beans, nuts and seeds; some lean meats, fish, eggs, low- fat dairy products; and mono and polyunsaturated oils. Limit intake of saturated fat, cholesterol, salt, alcohol and an excess of added sugars and sugary foods. Drink plenty of water. Maintain a normal weight. Exercise regularly. Recommended dietary intakes or allowances (RDI or RDA) are set by authorities for all essential nutrients . Older adults may also have special requirements and recommended intakes. Weight Training Nutrition. People who exercise have different requirements to sedentary people because the greater expenditure of energy usually requires a greater intake of food. The more you exercise the more you have to eat to sustain that level of activity to the point where some elite athletes such as Tour de France cyclists need to eat huge quantities of food to sustain their activity. Simple enough, and this also applies to casual exercisers, but it may not apply to you if fat loss is one of the reasons you took up weight training. Nutrition for weight loss. In this case, you need to create an energy deficit; which means that the energy you consume in food is less than the energy you expend in exercise and daily living. Creating a 1. 5 to 2. Your weight training, in this case, is to assist with fat loss while attempting to maintain muscle. Yet weight losers need to do the very tricky thing of holding onto muscle and bone while shedding fat. Breaking down is called catabolism and building up is called anabolism, as in anabolic steroids. This is a contradictory process. See my article How to Burn More Fat for an in- depth look at losing fat. That. If you weight train for sports, weight lifting competition, bodybuilding or even as a way to maintain fitness or appearance now that you. How much muscle you can gain, how quickly and with what definition is largely determined by your genetics and age. But everyone at almost any age should be able to gain some muscle and strength with weight training. Proper nutrition is a crucial element in the muscle building process. That overeating is not a good idea if you are already overweight is surely something you already know. Get fit first. When you overeat for the purposes of gaining muscle you also gain some fat. Increase your daily intake of energy (calories) by about 1. Diet Plans; Recipes; Meal Planning; Supplementation. Here's what to keep in mind when training the rear delts. 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You could do this with guesswork or you could work out your normal requirements using various formulae on the net and then increase food intake accordingly. Try Joanne Larsen's terrific Healthy Body Calculator. It should not be all protein but the extra protein you consume, either in supplements or protein foods, should be low in fat. More on this later in the article, but you should stay close to the current guidelines for protein requirements for weight trainers. Hiring a sports dietitian with some experience in weight training is also an option. Commence a solid weight training program targeting all the main large muscle groups such as the arms, legs, shoulders, chest, back, and abdominals. The extra energy you consume will fuel muscle growth as the exercise stimulates growth. This mean that you are now bulked up with extra muscle and fat, and you need to lose much of that fat while maintaining the muscle. Gaining fat is somewhat inevitable during this process but you should be especially careful to eat healthy food at this time. Fast foods should be kept to a minimum. Eat healthy but big. Energy deficit revisited. Remember what I said about catabolism and anabolism previously in relation to weight loss? You are now going to attempt to do just that: shed fat and hold onto the lovely muscle you gained. Your energy intake should now be cut back by the 1. Because you're now not the lean guy you once were, you may have to eventually eat slightly more to maintain that extra muscle, but not right now. This is a slightly different scenario to someone who is obese, unfit and trying to lose weight and hold muscle. Our young and fit male weight trainer has a more normal hormonal metabolism but he still has to do this correctly. In fact, bodybuilders do this sort of thing regularly to prepare themselves for competition: they put on muscle and some fat by eating up, then they strip off the fat leaving the muscle to show through. For example, if your protein intake was 1 gram/pound of your body weight per day (2. Such a nutrition plan could look like this for the macronutrients (protein, fat, carbohydrate): Bulking phase. Protein: 1. 5- 2. Fat: 2. 0- 3. 0%Carbohydrate: 5. Cutting phase. Protein: 2. Fat 1. 5- 2. 0%Carbohydrate 5. In either phase, you really don. A little more probably won. Any hint of kidney disease and you would need to be cautious about excessive protein intake. Consult your doctor for advice if this applies. I emphasize protein intake because the tendency of some male weight trainers is to shovel in the protein in the form of shakes and supplements and the occasional whole turkey without figuring out how much is useful or even how much they are ingesting. The numbers above are actually at the top of the range of possible requirements. The American College of Sports Medicine estimates the requirements for strength trainers at 1. If you don't do high intensity or long sessions, and only a few days a week, this is likely to be in excess of requirements as well. Meal Timing for Bodybuilding Diets. Now that you. Eating for elite athletes is taken very seriously by sports nutritionists and coaches . Even in the amateur ranks it. Meal timing and constitution before and after exercise is an important part of this. The Pre- exercise Meal. Weight trainers don. For example, a heavy- training marathoner or triathlete may require 7- 1. Take it from me that this is a lot of carbohydrates . Remember, this is for eating before you train or compete. Experiment and find your tolerance for various foods before and during exercise. This is important because many of us react differently to fiber, foods like beans, milk, various fruits and so on. Eat meals low in fat and fiber with some protein and carbohydrate. Fiber can and should be part of a healthy diet in other meals. The main meal should be eaten 3- 4 hours before exercise. A smaller meal can be taken 1- 2 hours before exercise. Within an hour of activity, liquids such as sports drinks and gels, or protein shakes or foods that are not too heavy may be best. A very small percentage of people get a reactive blood glucose drop if they eat a high carbohydrate meal, so this may not be suitable for some people near to exercise. The number of athletes that suffer from this condition, called hypoglycemia, is much lower than once thought. Adding protein to the meal can prevent this. Running type sports seem to churn the gut up and produce discomfort more than stationary or supported sports like weight training, swimming or cycling; so the pre- meal variety can be greater if you. Research has shown that an intake of 6- 1. One gram per kilogram body weight (about 0. Some trainers call this a protein 'shooter'. Here are some foods and combinations that provide at least 1. Flavored low- fat milk, 1. FL. And good shape means not letting your blood and muscle glucose get too low at which point cortisol and other hormones will be looking to break down your muscle. It's a fine point but one that's worth considering. You don't need expensive and probably useless supplements to protect you from catabolic cortisol surges, all you need is some carbohydrate from a sports drink, gel or bar. The Post- Exercise Meal. How you eat to recover from exercise is one of the most important principles in exercise nutrition. Glucose is the athlete. You get it from carbohydrate foods and drinks. What's more, inadequate refueling after your session won't take advantage of that hard muscle work by giving those muscles an anabolic boost that repairs and builds. Weight trainers do not use as much glucose fuel as the higher intensity or higher duration aerobic sports like track and endurance running and cycling, but even so, it pays to keep those glycogen stores topped up if you want to be at your best in training. You will notice glucose depletion more after muscle endurance and hypertrophy programs where higher repetitions, perhaps to failure, are slated rather than the low- rep strength sets where direct ATP (adenosine triphosphate) is likely the main fuel. Low numbers of repetitions with heavy weights are used to develop strength, whereas lighter weights and more repetitions are used to build muscle size and muscle endurance. The latter is likely to expend more energy. Here is how to recover after your workout. Commence recovery nutrition within 3. Consume protein as soon as possible: 1. Consume carbohydrate as soon as possible: one gram per kilogram body weight (0. 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